Spoilers: (Highlight to reveal) Sindel stays evil, it seems. Scorpion is also portrayed as a villain, guarding Quan Chi from Raiden. We both know that'll change though.
Neutral Guys MK1 Sub-Zero Scorpion Ermac (If you consider the Error Macro in MK1 to be cannon)
Bad Guys MK1 Shang Tsung Goro Kano Reptile
MORTAL KOMBAT 2
Good Guys MK2 Raiden Liu Kang Johnny Cage Kung Lao Jax Sub-Zero Sonya (Chained to a pedestal...but hey she was still there)
Neutral Guys MK2 Smoke Noob Saibot Scorpion
Bad Guys MK2 Shao Kahn (Uhh,,,,duhhh) Kintaro Shang Tsung Reptile Baraka Mileena Kitana (Starts off bad but turns good at some point in MK2) Jade
MORTAL KOMBAT 3 Gonna list the Ultimate version because uhhh it was ULTIMATE
Good guys UMK3 Liu Kang Kung Lao Sonya Jax Sub-Zero Nightwolf Stryker Kabal Kitana
Neutral Guys UMK3 Noob Saibot Robot Smoke
Bad Guys UMK3 Shao Kahn Motaro Shang Tsung Sindel (Turns good after UMK3 when Shao Kahn's beaten) Mileena Jade (Starts off Bad but then turns good) Scorpion (Works for Kahn but when he sees Sub-Zero he turns on Kahn and goes back to being neutral) Ermac Reptile Rain Sheeva Cyrax (Starts off bad but Sub-Zero turns him into a neutral character) Sektor